You should first verify compression. Valve lash is common for a hard to start situation especially a tight intake valve. It also may be dropping spark? Could have an airboot leaking and leaning it out to the point that it doesnt want to run. If you can, test fuel pressure. The injector is probably the last component I would check after verifying these first. In a shop, the typical tests would go about in the order of:
1. compression/leakdown 2. spark 3. fuel pressure. One of these would usually point to the system to dig into further